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FM-200® and CO2 are two of the most effective forms of fire suppression, and in facilities from power plants to clean rooms, they will work when water is just not an option.
FM-200 need smaller storage area.
Apart from what others have answered here , i would like to add FM200 is an automated fire suppression system whereas co2 type is not. Recently i came across one more system where oxygen level @data centers or other secured places are being controlled(14-15%)to avoid fire. its called CAP9 system.
FM200 is1,1,1,2,3,3,3 heptafluoro propane. It's in the chemical family of halons, which suppress fire by interfering catalytically with combustion reactions. They can do this at relatively low concentrations which do not constitute a hazard to humans. This means that the site of a fire can be checked out by people without protective gear without the threat of re-ignition.
Carbon dioxide just displaces oxygen. If CO2 is in sufficient concentration to suppress fire, the area will be off-limits to human without breathing gear. This causes some problems with safety checks afterward.
FM CAN WORK IN VERY LOW TEMPRATURE ( - DIGREE CELCIOUS ) BUT CO2 CAN NOT