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Offer him additional benefits, salary or allowances that may take him/her back, but in the end we always know that employee have the rights to choose what would be the best for him/her.
If the employee is willing for a frank discussion, have it with involvement flexibility and leniency . In the mean time review the situations that might have lead him to take such a decision. If there is a positive sign from him to continue happily accept it, otherwise it would be better to allow him to relieve with all his terminal benefits promptly paid.