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there are not much deference between CS versions of Photoshop, i prefer you to start learning photoshop CS6 as a beginner. there are lots of free tutorials out there in youtube.
Learning photoshop through tutorials will make the learning experience to be much more fun since you can learn new skills at your own pace. Also one advantage is that you can skip any tutorials according to your needs. You just have to to find the right site that suits your specific skills.
TRY ASKING YOU TUBE, ITS GONNA HELP FOR SURE AND I DON'T SEE ANY POINT LEARNING PHOTOSHOP IF YOU AIN'T INTO THAT FIELD OF ART OR WORK.