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Portfolio is build based on individual risk and return preferences.
IRR is where NPV is equal to amount spend.
NPV is the difference beteween the present value of future cash flows arising out of a project and the present value of investments.
IRR is the rate of return at which NPV =0
In other words, you will get what you have spent on the project.
For finding out IRR, you have to keep NPV=0 and the find out the rate through Trial and Error method..
If a project has positive NPV, we can go for it given that IRR>cost of capital
Now if NPV and IRR are contradictory to each other, go with NPV value
Now coming to the other question, individuals' risk taking ability decides the portfolio composition as well. When we go for preparation of portfolio, we must consider the risk tolerance of the investor and must decide how the portfolio must be diversified.