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Both have their Pros and Cons. I would prefer a Skype one as it provides additional flexibility.
Both are equal according to the current trend. It is now adays, the convenience matters most.
I believe a face to face interview is always better than a Skype round if the circumstances allow for it.
Face to Face helps the two people to discuss in detail regarding the profile, in the beginning the interviewee may feel a little uncomfortable but eventually face to face is the best way to break the ice.