Register now or log in to join your professional community.
Pressure:This only applies to reactions involving gases:
Temperature:
For this, you need to know whether heat is given out or absorbed during the reaction. Assume that our forward reaction is exothermic (heat is evolved):
This shows that 250 kJ is evolved (hence the negative sign) when 1 mole of A reacts completely with 2 moles of B. For reversible reactions, the value is always given as if the reaction was one-way in the forward direction.
The back reaction (the conversion of C and D into A and B) would be endothermic by exactly the same amount.
For gases the basic principle is ideal qas low.
Pressure (symbol: p or P) is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled gage pressure)[a] is the pressure relative to the ambient pressure.
Various units are used to express pressure. Some of these derive from a unit of force divided by a unit of area; the SI unit of pressure, the pascal (Pa), for example, is one newton per square metre; similarly, the pound-force per square inch (psi) is the traditional unit of pressure in the imperial and US customary systems. Pressure may also be expressed in terms of standard atmospheric pressure; the atmosphere (atm) is equal to this pressure and the torr is defined as 1⁄760 of this. Manometric units such as the centimetre of water, millimetre of mercury, and inch of mercury are used to express pressures in terms of the height ofcolumn of a particular fluid in a manometer.
A temperature is an objective comparative measure of hot or cold. It is measured by a thermometer, which may work through the bulk behavior of a thermometric material, detection of thermal radiation, or particle kinetic energy. Several scales and units exist for measuring temperature, the most common being Celsius (denoted °C; formerly called centigrade), Fahrenheit (denoted °F), and, especially in science, Kelvin (denoted K).