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YES offcource being an HR PROFESSIONAL, one of your duty and responsibilities is to recieve any e mail or CV's from applicant if thier is any vacancies hired,it's your obligation to recieve and check any data from willing applicants so that you have an idea just in case your going to give them interview after checking each applicant personal background.
I prefer, if there is a vacancy, to apply online to the post; or if it is an ad, you follow the method pointed in the ad for applying. In case you are trying to submit your CV to be in the organisation data base for any future vacancy, I prefer also to apply online to keep your application on the organisation portal and not to be missed.