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You have to follow whats in the vacancey announcement.
I suggest to do both because both has it's own advantage. As for me, I send my CV through emails more often because living in a modern generation, hiring process has upgraded hence HR management searching applicants online. However, for guarantee, it is also good to distribute physical copy of your CV to companies.
Thanks
It depends on company recruitment policies, but in my opinion via e-mail.
2_ GO to the work position