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The answer is Big YES , in my work history i didn't find any where can't apply it , even in the serivce fields its required as well, as its the concept of AP cycle.
Ofcourse3 way matching is an integral part of AP in order to excircise a strict control and fraudulent practices. There are some instances in which GRN may not be available oru the services are hired on a Payment on Approval (POA) basis. In such circumstances only2way matching is only possible.