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from the file tab then options at general change the username
In Excel2013 ............. Go on File; Options, then in middle it gives options to change user!!
The same would be for Word and PowerPoint.
This feature may come with MS Office360, right ?
I AGRRE WITH MR AHMED MAHR ANSWER
In Office2013 - File > Options > Office Account > make edit to user if you are signed in by MS account.
Locally can be changed - File > Options > General > Personalize your copy ... and change username.