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Which companies based on its size are more attended to use one of the following PHP or .net ?
C# and VB.net for .NET (ASPx)
PHP is much like C++, so easy to start with - FREE.
Regarding Egypt - you can search on bayt.com for the job opportunities and skills they require.
Remember - These opportunities were listed by "people may be experienced". People influence a use/misuse of particular technologies and there's always a scope for change. In-fact everything irons out (becomes more wrinkle-free) as a new decision maker takes over. So one should not worry too much about what is being currently used in "Egypt'. Rather look at what is trending best across the globe - eventually that is going to rule in all the pockets of the world.
C# can be used for the development of ASP.NET Web Applications while PHP is whole new language, regarding to more common in Egypt, I think that does'nt matter what matters is your programmic logic and understanding, i think both have equal opportunities however i want to mention that PHP is slighlty more popular than ASP.NET worldwide as the developer community is bigger than ASP.NET