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Do you know about our requirements for that job?
There could be multiple questions depending upon the situation and position but there are some generic one;
1 - To break the ice, i usually ask Tell us some thing about yourself?
2 - How do you add value to us?
3 - Your major strength & opportunity area in personality.
4 - What you know about our company.
What accomplishments did you achieve, and how did you achieve them?
What do you see yourself doing within the first year of this job?
What do you know about our organization?