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It all depends on the load-bearing
1 ratio sand3 aggragates5 ratio of cement
Its depend upon the mix requirement and fine to coarse curve as per ASTM finally for the Columns it is prefer to have fine mix rather than coarse mix
check grade of concrete specified for column, after knowing the grade of concrete you know required characteristics strength.. now you can follow guidelines for concrete mix to design concrete for particular strength, whatever you are doing take help of locally available concrete professional.
Defend on design strength of column