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Sure. And using SAMBA package, it can appear as a windows file server.
Very Well,
1. For SMB Network you can use samba as fileserver.
2. for unix/linux based NFS share you can export files natively if you have installed nfs-server related packages.
3. for AFP [ AppleTalk ] you can use netatalk to configure the file and print shares.
Hope that answers.
You can use VSFTPD as File server.
https://www.digitalocean.com/community/articles/how-to-set-up-vsftpd-on-centos-6--2
If you want to access it from Windows then use Samba:
http://wiki.centos.org/HowTos/SetUpSamba
go and configure SAMBA on Cent OS .
http://www.howtoforge.com/centos-6.4-samba-standalone-server-with-tdbsam-backend
you can do it using SAMBA
Yes you can use redhat OS as a file server by installing the appropriate package vsftpd-*.rpm and configure iptables to autorize access from external .
yum install vsftpd -y
chkconfig vsftpd on
system-config-firewall
select ftp service as trusted service.
the simple answer of your question is simply "YES"