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HR obviously stand for "Human Resources" and it is in simple terms the management of employees and personnel in the company. That could include, but is not limited to, managing the work schedules, following up with working hours, following up with sick leaves as well as personal leave requests, and generally anything to do with the personnel themselves.
However, as an administrator, your job will most likely revolve around working within the office. Filing certain documents, making sure all the office equipment is functional, requesting any stationary that is missing from the office, scheduling meetings, and your job tasks may include operational management tasks.