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If the office gives them time, then it is possible to do such works. In today's world, due to working more than12 hour a day (including weekends for some organisations) there is no time to handle personal life, then how can anyone think of social works?
The only option is to do it during vacation. This is because, social works require your personal presence to oversee such matters and it takes a lot of time for this. If you pay a cancer centre some amount, it does carry some value, but if you spend time with cancer patients and understanding their pain, then you will be of so much value which no money can substitute.
The other way is to do it collectively during office hours as a group with the permission of the management and involving them to support good causes, for which office personnel can spent time on.