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It is an ability of a process to meet customer's specifications without generating defects beyond acceptable limits, through the evaluation of the spread and centering of the process.
This study is done by evaluating
"How precise the measured data from the lot?" (Cp) - Done by studying how the close the data points are towards the average - Spread of the process.
and
"How accurate the measured data from the lot?" (CpK) - Done by studying how close the average towards the centre - Closer to the target, higher the CpK as more area of the curve false within the spec limits.
Process capability compares the output of an in-control process to the specification limits by using capability indices.
It can be described as the capability of a process to meet its purpose.
In enigneering/production the process capability indicates how the output of the process meets the requirements (for example engineering tolerances, customer requirements, etc.)
For IT processes ISO15504 describes a measurement framework to assess process capability.